Study of the water oxidation mechanism by ruthenium(ii) complexes containing N-heterocyclic ligands
Recent researches and elucidation of new ruthenium catalysts containing N-heterocyclic ligands have shown great importance and relevance in the study of water oxidation kinetics and its mechanisms, which produces O2 coupled with protons and electrons transfer through the catalytic cycle. In this pro...
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| Main Authors: | , , , |
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| Format: | Online |
| Language: | Portuguese |
| Published: |
Universidade Estadual de Campinas
2019
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| Subjects: | |
| Online Access: | https://econtents.sbu.unicamp.br/eventos/index.php/pibic/article/view/2314 |
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| Summary: | Recent researches and elucidation of new ruthenium catalysts containing N-heterocyclic ligands have shown great importance and relevance in the study of water oxidation kinetics and its mechanisms, which produces O2 coupled with protons and electrons transfer through the catalytic cycle. In this project, we are working with a new complex [Ru(H2dimpy)(phen)Cl]PF6 (where H2dimpy = 2,6-bis(1H-imidazol2-yl)pyridine and phen = 1,10-phenanthroline), which was synthezed and characterized by 1H NMR, FTIR, UV-vis and elemental analysis. |
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| ISSN: | 2596-1969 |
