Study of water oxidation and oxygen reduction reactions by prussian blue and cnalogues compounds

Electrocatalytic processes of water oxidation and oxygen reduction reactions are getting highlighted due to its importance in the development of electrochemical systems to convert and store energy. Oxygen reduction reaction (ORR) in acid and alkaline aqueous solutions demonstrate kinetics and thermo...

Full description

Saved in:
Bibliographic Details
Main Authors: Doretto, Daniel, Bonacin, Juliano, Zambiazi, Priscilla, Aparecido, Gabriel
Format: Online
Language:Portuguese
Published: Universidade Estadual de Campinas 2019
Subjects:
Online Access:https://econtents.sbu.unicamp.br/eventos/index.php/pibic/article/view/2651
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Electrocatalytic processes of water oxidation and oxygen reduction reactions are getting highlighted due to its importance in the development of electrochemical systems to convert and store energy. Oxygen reduction reaction (ORR) in acid and alkaline aqueous solutions demonstrate kinetics and thermodynamic complexity. In sight of that, electrocatalytic analysis of the Fe II 3 [Fe III (CN) 6 ] 2 ( PB ) and Co II 3 [Fe III/II (CN) 6 ] 2 ( Co-PBA ) thin films (prepared by electrodeposition) for water oxidation reaction (WOR) and oxygen reduction reaction (ORR) were evaluated in acid aqueous solution and in KCl (0.1M) and KNO 3 (0.5M) electrolytes. The PBAs catalysts thin films are highly stable and capable of keeping its catalytic activities during several cycles.
ISSN:2596-1969