Epitaxial graphene on SiC(0001): a photoelectron diffraction study

A flat, single layer of graphite known as graphene has become the focus of studies due to its exceptional properties and fascinating applications. Large scale graphene layers for a possible application can be grown epitaxially on SiC by Si sublimation [1]. Even before the interest in graphene, the s...

ver descrição completa

Na minha lista:
Detalhes bibliográficos
Autor principal: Lima , Luis Henrique de
Formato: Online
Idioma:português
Publicado em: Universidade Estadual de Campinas 2020
Assuntos:
Acesso em linha:https://econtents.sbu.unicamp.br/eventos/index.php/phyproceedings/article/view/3250
Tags: Adicionar Tag
Sem tags, seja o primeiro a adicionar uma tag!
_version_ 1864358293879652352
author Lima , Luis Henrique de
author_facet Lima , Luis Henrique de
author_sort Lima , Luis Henrique de
collection Portal de Eventos Científicos da UNICAMP
container_reference Physicae Proceedings; Vol. 1 No. 1 (2012): Proceedings XI Young Researchers Meeting ; 1-1
description A flat, single layer of graphite known as graphene has become the focus of studies due to its exceptional properties and fascinating applications. Large scale graphene layers for a possible application can be grown epitaxially on SiC by Si sublimation [1]. Even before the interest in graphene, the surface of SiC was already extensively studied [2],[3]. It exhibits a large variety of surface reconstructions and these reconstructions are very dependent of sample preparation and orientation (0001) or (000-1). In this study, we show a investigation of the structural properties of graphene layers on SiC (0001) by photoelectron diffraction (XPD). The surfaces were prepared by heating the 1x1 surface to temperatures of about 1150 in high ultra vacuum and the various reconstructions were monitored by Low Energy Electron Diffraction (LEED) and X-Ray Photoelectron Spectroscopy (XPS). In particular for the Si terminated surface, that is SiC(0001), the interface between graphene and SiC is characterized by the so-called (6Sqrt(3) × 6Sqrt(3))R30? reconstruction (buffer layer). The interpretation of this reconstruction, which is the initial stage of graphitization, has lead to controversy in the literature [2]. We will further discuss the buffer layer structure in terms of the XPD results. The XPD experiments were performed at SGM beam line at LNLS using photons with 450 eV probing the Si2p and C1s core level. The C1s signal was separate in to contributions from volume and surface and compares the experimental results with photoelectron multiple scattering calculations performed with the MSCD package [4].
first_indexed 2025-10-08T13:49:18Z
format Online
id ojs-article-3250
institution Universidade Estadual de Campinas
issn 2236-7535
language por
last_indexed 2025-10-08T13:49:18Z
publishDate 2020
publisher Universidade Estadual de Campinas
record_format ojs
spelling ojs-article-32502020-05-15T15:30:07Z Epitaxial graphene on SiC(0001): a photoelectron diffraction study Lima , Luis Henrique de Photoelectron diffraction Graphene A flat, single layer of graphite known as graphene has become the focus of studies due to its exceptional properties and fascinating applications. Large scale graphene layers for a possible application can be grown epitaxially on SiC by Si sublimation [1]. Even before the interest in graphene, the surface of SiC was already extensively studied [2],[3]. It exhibits a large variety of surface reconstructions and these reconstructions are very dependent of sample preparation and orientation (0001) or (000-1). In this study, we show a investigation of the structural properties of graphene layers on SiC (0001) by photoelectron diffraction (XPD). The surfaces were prepared by heating the 1x1 surface to temperatures of about 1150 in high ultra vacuum and the various reconstructions were monitored by Low Energy Electron Diffraction (LEED) and X-Ray Photoelectron Spectroscopy (XPS). In particular for the Si terminated surface, that is SiC(0001), the interface between graphene and SiC is characterized by the so-called (6Sqrt(3) × 6Sqrt(3))R30? reconstruction (buffer layer). The interpretation of this reconstruction, which is the initial stage of graphitization, has lead to controversy in the literature [2]. We will further discuss the buffer layer structure in terms of the XPD results. The XPD experiments were performed at SGM beam line at LNLS using photons with 450 eV probing the Si2p and C1s core level. The C1s signal was separate in to contributions from volume and surface and compares the experimental results with photoelectron multiple scattering calculations performed with the MSCD package [4]. Universidade Estadual de Campinas 2020-05-15 info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion application/pdf https://econtents.sbu.unicamp.br/eventos/index.php/phyproceedings/article/view/3250 Physicae Proceedings; Vol. 1 No. 1 (2012): Proceedings XI Young Researchers Meeting ; 1-1 Physicae Proceedings; v. 1 n. 1 (2012): Proceedings XI Young Researchers Meeting ; 1-1 2236-7535 por https://econtents.sbu.unicamp.br/eventos/index.php/phyproceedings/article/view/3250/3186 Copyright (c) 2012 Physicae
spellingShingle Lima , Luis Henrique de
Photoelectron diffraction
Graphene
Epitaxial graphene on SiC(0001): a photoelectron diffraction study
title Epitaxial graphene on SiC(0001): a photoelectron diffraction study
title_full Epitaxial graphene on SiC(0001): a photoelectron diffraction study
title_fullStr Epitaxial graphene on SiC(0001): a photoelectron diffraction study
title_full_unstemmed Epitaxial graphene on SiC(0001): a photoelectron diffraction study
title_short Epitaxial graphene on SiC(0001): a photoelectron diffraction study
title_sort epitaxial graphene on sic(0001): a photoelectron diffraction study
topic Photoelectron diffraction
Graphene
url https://econtents.sbu.unicamp.br/eventos/index.php/phyproceedings/article/view/3250
work_keys_str_mv AT limaluishenriquede epitaxialgrapheneonsic0001aphotoelectrondiffractionstudy