Physical properties of Sb2 O3 - P2 O5 glasses

Some physical properties of a Sb2 O3 -P2 O5 glass were analyzed. A glass with composition (mol%) 75Sb2 O3 25P2 O5 were melted in an electrical furnace and in glassy carbon crucible at 1000 . Samples were cutted, lapped and polished with cerium oxide and using ethylene glycol as polishing fluid, sinc...

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Main Author: Paula , Marina Heleno Fernandes de
Format: Online
Language:Portuguese
Published: Universidade Estadual de Campinas 2020
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Online Access:https://econtents.sbu.unicamp.br/eventos/index.php/phyproceedings/article/view/3253
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author Paula , Marina Heleno Fernandes de
author_facet Paula , Marina Heleno Fernandes de
author_sort Paula , Marina Heleno Fernandes de
collection Portal de Eventos Científicos da UNICAMP
container_reference Physicae Proceedings; Vol. 1 No. 1 (2012): Proceedings XI Young Researchers Meeting ; 1-1
description Some physical properties of a Sb2 O3 -P2 O5 glass were analyzed. A glass with composition (mol%) 75Sb2 O3 25P2 O5 were melted in an electrical furnace and in glassy carbon crucible at 1000 . Samples were cutted, lapped and polished with cerium oxide and using ethylene glycol as polishing fluid, since the glass presents some hygroscopicity. Using the Archimedes principle and ethylene glycol again as immersion fluid, the density of the glass was determined to be ?= (4,774±0,001) g/cm^3. The pulse-echo method was applied to determine the longitudinal and transversal ultrasonic velocities. These values enable the calculation of the Young modulus, E, and the Poisson coefficient, ?: E = (39±2) GPa and ? = 0,22±0,01. The experimental value of the hardness was obtained from measurements of the Vickers impression diagonals, d, produced by applying loads, P , up to 500 g: H = (2,31±0,04) GPa. Dilatometric measurements indicate that the glass transition temperature, Tg, is about 300 , and the dilatometric softening temperature, Td, is 330 . The coefficient of thermal expansion, ?, between 150 and 270 is 17.3 x 10?6 °?1 . Once the glass is transparent, the refractive index was obtained by using an optical microscope. This values is roughly given: n = (1,96±0,08). Therefore one can conclude that, although the low values of the Young modulus and hardness, the high value of the refractive index demonstrates that this glass can present interesting optical applications.
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spelling ojs-article-32532020-05-15T15:30:07Z Physical properties of Sb2 O3 - P2 O5 glasses Paula , Marina Heleno Fernandes de Fluid Ultrasonic velocities Some physical properties of a Sb2 O3 -P2 O5 glass were analyzed. A glass with composition (mol%) 75Sb2 O3 25P2 O5 were melted in an electrical furnace and in glassy carbon crucible at 1000 . Samples were cutted, lapped and polished with cerium oxide and using ethylene glycol as polishing fluid, since the glass presents some hygroscopicity. Using the Archimedes principle and ethylene glycol again as immersion fluid, the density of the glass was determined to be ?= (4,774±0,001) g/cm^3. The pulse-echo method was applied to determine the longitudinal and transversal ultrasonic velocities. These values enable the calculation of the Young modulus, E, and the Poisson coefficient, ?: E = (39±2) GPa and ? = 0,22±0,01. The experimental value of the hardness was obtained from measurements of the Vickers impression diagonals, d, produced by applying loads, P , up to 500 g: H = (2,31±0,04) GPa. Dilatometric measurements indicate that the glass transition temperature, Tg, is about 300 , and the dilatometric softening temperature, Td, is 330 . The coefficient of thermal expansion, ?, between 150 and 270 is 17.3 x 10?6 °?1 . Once the glass is transparent, the refractive index was obtained by using an optical microscope. This values is roughly given: n = (1,96±0,08). Therefore one can conclude that, although the low values of the Young modulus and hardness, the high value of the refractive index demonstrates that this glass can present interesting optical applications. Universidade Estadual de Campinas 2020-05-15 info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion application/pdf https://econtents.sbu.unicamp.br/eventos/index.php/phyproceedings/article/view/3253 Physicae Proceedings; Vol. 1 No. 1 (2012): Proceedings XI Young Researchers Meeting ; 1-1 Physicae Proceedings; v. 1 n. 1 (2012): Proceedings XI Young Researchers Meeting ; 1-1 2236-7535 por https://econtents.sbu.unicamp.br/eventos/index.php/phyproceedings/article/view/3253/3189 Copyright (c) 2012 Physicae
spellingShingle Paula , Marina Heleno Fernandes de
Fluid
Ultrasonic velocities
Physical properties of Sb2 O3 - P2 O5 glasses
title Physical properties of Sb2 O3 - P2 O5 glasses
title_full Physical properties of Sb2 O3 - P2 O5 glasses
title_fullStr Physical properties of Sb2 O3 - P2 O5 glasses
title_full_unstemmed Physical properties of Sb2 O3 - P2 O5 glasses
title_short Physical properties of Sb2 O3 - P2 O5 glasses
title_sort physical properties of sb2 o3 - p2 o5 glasses
topic Fluid
Ultrasonic velocities
url https://econtents.sbu.unicamp.br/eventos/index.php/phyproceedings/article/view/3253
work_keys_str_mv AT paulamarinahelenofernandesde physicalpropertiesofsb2o3p2o5glasses