A Gaussian conduction carrier EPR line

Analyzing the EPR spectra of a selfstanding conducting polymer film we noticed the asymmetry of the first derivative of the EPR line, suggesting that we should use a Dysonian line. This Dysonian line can be represented by a combination of absorption and dispersion Lorentzian lines. However we notice...

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Main Author: Santana , Vinicius Tadeu
Format: Online
Language:Portuguese
Published: Universidade Estadual de Campinas 2020
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Online Access:https://econtents.sbu.unicamp.br/eventos/index.php/phyproceedings/article/view/3258
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author Santana , Vinicius Tadeu
author_facet Santana , Vinicius Tadeu
author_sort Santana , Vinicius Tadeu
collection Portal de Eventos Científicos da UNICAMP
container_reference Physicae Proceedings; Vol. 1 No. 1 (2012): Proceedings XI Young Researchers Meeting ; 1-1
description Analyzing the EPR spectra of a selfstanding conducting polymer film we noticed the asymmetry of the first derivative of the EPR line, suggesting that we should use a Dysonian line. This Dysonian line can be represented by a combination of absorption and dispersion Lorentzian lines. However we noticed that adding a small Gaussian line would improve the fitting. Hence, due to the skin depth, we introduced numerically a dispersion contribution to this absorption Gaussian line according to G. E. Pake and E. M. Purcell (Phys. Rev. 74, 1184–1188 (1948)). To our knowledge, this is the first time that this dispersive contribution of the Gaussian line has been introduced in the analysis of the EPR spectrum.
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institution Universidade Estadual de Campinas
issn 2236-7535
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spelling ojs-article-32582020-05-15T15:30:07Z A Gaussian conduction carrier EPR line Santana , Vinicius Tadeu Selfstanding conducting polymer Dysonian line Analyzing the EPR spectra of a selfstanding conducting polymer film we noticed the asymmetry of the first derivative of the EPR line, suggesting that we should use a Dysonian line. This Dysonian line can be represented by a combination of absorption and dispersion Lorentzian lines. However we noticed that adding a small Gaussian line would improve the fitting. Hence, due to the skin depth, we introduced numerically a dispersion contribution to this absorption Gaussian line according to G. E. Pake and E. M. Purcell (Phys. Rev. 74, 1184–1188 (1948)). To our knowledge, this is the first time that this dispersive contribution of the Gaussian line has been introduced in the analysis of the EPR spectrum. Universidade Estadual de Campinas 2020-05-15 info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion application/pdf https://econtents.sbu.unicamp.br/eventos/index.php/phyproceedings/article/view/3258 Physicae Proceedings; Vol. 1 No. 1 (2012): Proceedings XI Young Researchers Meeting ; 1-1 Physicae Proceedings; v. 1 n. 1 (2012): Proceedings XI Young Researchers Meeting ; 1-1 2236-7535 por https://econtents.sbu.unicamp.br/eventos/index.php/phyproceedings/article/view/3258/3194 Copyright (c) 2012 Physicae
spellingShingle Santana , Vinicius Tadeu
Selfstanding conducting polymer
Dysonian line
A Gaussian conduction carrier EPR line
title A Gaussian conduction carrier EPR line
title_full A Gaussian conduction carrier EPR line
title_fullStr A Gaussian conduction carrier EPR line
title_full_unstemmed A Gaussian conduction carrier EPR line
title_short A Gaussian conduction carrier EPR line
title_sort gaussian conduction carrier epr line
topic Selfstanding conducting polymer
Dysonian line
url https://econtents.sbu.unicamp.br/eventos/index.php/phyproceedings/article/view/3258
work_keys_str_mv AT santanaviniciustadeu agaussianconductioncarriereprline
AT santanaviniciustadeu gaussianconductioncarriereprline