Design of poly-functionalized catalysts and additives for the Morita-Baylis-Hillman reaction

In this work we developed a new syntetic approach for the preparation of bi-functional catalysts derived from imidazole, without conformational constraints and having a center acting as Lewis base and other as Bronsted acid. These new catalysts were prepared in three steps, in overall yields ranging...

Full description

Saved in:
Bibliographic Details
Main Authors: Reis, Lucas Grijó dos, Coelho, Fernando Antonio Santos, Zeoly, Lucas André
Format: Online
Language:English
Published: Universidade Estadual de Campinas 2019
Subjects:
Online Access:https://econtents.sbu.unicamp.br/eventos/index.php/pibic/article/view/885
Tags: Add Tag
No Tags, Be the first to tag this record!
_version_ 1864358624256589824
author Reis, Lucas Grijó dos
Coelho, Fernando Antonio Santos
Zeoly, Lucas André
author_facet Reis, Lucas Grijó dos
Coelho, Fernando Antonio Santos
Zeoly, Lucas André
author_sort Reis, Lucas Grijó dos
collection Portal de Eventos Científicos da UNICAMP
container_reference Revista dos Trabalhos de Iniciação Científica da UNICAMP; n. 26 (2018): Congresso de Iniciação Científica Unicamp
description In this work we developed a new syntetic approach for the preparation of bi-functional catalysts derived from imidazole, without conformational constraints and having a center acting as Lewis base and other as Bronsted acid. These new catalysts were prepared in three steps, in overall yields ranging from 15% to up 48%, using Morita-Baylis-Hillman adducts as building blocks.
first_indexed 2025-10-08T13:52:28Z
format Online
id ojs-article-885
institution Universidade Estadual de Campinas
issn 2596-1969
language eng
last_indexed 2025-10-08T13:52:28Z
publishDate 2019
publisher Universidade Estadual de Campinas
record_format ojs
spelling ojs-article-8852025-09-26T14:32:30Z Design of poly-functionalized catalysts and additives for the Morita-Baylis-Hillman reaction Reis, Lucas Grijó dos Coelho, Fernando Antonio Santos Zeoly, Lucas André Morita-Baylis-Hillman Lewis bases Organocatalysis. In this work we developed a new syntetic approach for the preparation of bi-functional catalysts derived from imidazole, without conformational constraints and having a center acting as Lewis base and other as Bronsted acid. These new catalysts were prepared in three steps, in overall yields ranging from 15% to up 48%, using Morita-Baylis-Hillman adducts as building blocks. Universidade Estadual de Campinas 2019-02-12 info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion Artigo de convidado application/pdf https://econtents.sbu.unicamp.br/eventos/index.php/pibic/article/view/885 10.20396/revpibic262018885 Revista dos Trabalhos de Iniciação Científica da UNICAMP; n. 26 (2018): Congresso de Iniciação Científica Unicamp 2596-1969 eng https://econtents.sbu.unicamp.br/eventos/index.php/pibic/article/view/885/955 Copyright (c) 2019 Lucas Grijó dos Reis, Fernando Antonio Santos Coelho http://creativecommons.org/licenses/by/4.0
spellingShingle Reis, Lucas Grijó dos
Coelho, Fernando Antonio Santos
Zeoly, Lucas André
Morita-Baylis-Hillman
Lewis bases
Organocatalysis.
Design of poly-functionalized catalysts and additives for the Morita-Baylis-Hillman reaction
title Design of poly-functionalized catalysts and additives for the Morita-Baylis-Hillman reaction
title_full Design of poly-functionalized catalysts and additives for the Morita-Baylis-Hillman reaction
title_fullStr Design of poly-functionalized catalysts and additives for the Morita-Baylis-Hillman reaction
title_full_unstemmed Design of poly-functionalized catalysts and additives for the Morita-Baylis-Hillman reaction
title_short Design of poly-functionalized catalysts and additives for the Morita-Baylis-Hillman reaction
title_sort design of poly-functionalized catalysts and additives for the morita-baylis-hillman reaction
topic Morita-Baylis-Hillman
Lewis bases
Organocatalysis.
url https://econtents.sbu.unicamp.br/eventos/index.php/pibic/article/view/885
work_keys_str_mv AT reislucasgrijodos designofpolyfunctionalizedcatalystsandadditivesforthemoritabaylishillmanreaction
AT coelhofernandoantoniosantos designofpolyfunctionalizedcatalystsandadditivesforthemoritabaylishillmanreaction
AT zeolylucasandre designofpolyfunctionalizedcatalystsandadditivesforthemoritabaylishillmanreaction