Continuous flow synthesis of terpene-based monomers for green polymers production

The synthesis of monomers for the production of novel green polymers was evaluated in continuous flow conditions using terpenes as dienes and maleic anhydride as dienophile for the [4+2] Diels-Alder cycloaddition reaction. The hydrogenation reaction was also evaluated to prevent the retro-Diels-Alde...

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Main Authors: Fernandes, Lucas Pera, Pastre, Julio Cezar, Galaverna, Renan, Gomes, Gustavo Rodrigues
Format: Online
Language:English
Published: Universidade Estadual de Campinas 2019
Subjects:
Online Access:https://econtents.sbu.unicamp.br/eventos/index.php/pibic/article/view/898
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author Fernandes, Lucas Pera
Pastre, Julio Cezar
Galaverna, Renan
Gomes, Gustavo Rodrigues
author_facet Fernandes, Lucas Pera
Pastre, Julio Cezar
Galaverna, Renan
Gomes, Gustavo Rodrigues
author_sort Fernandes, Lucas Pera
collection Portal de Eventos Científicos da UNICAMP
container_reference Revista dos Trabalhos de Iniciação Científica da UNICAMP; n. 26 (2018): Congresso de Iniciação Científica Unicamp
description The synthesis of monomers for the production of novel green polymers was evaluated in continuous flow conditions using terpenes as dienes and maleic anhydride as dienophile for the [4+2] Diels-Alder cycloaddition reaction. The hydrogenation reaction was also evaluated to prevent the retro-Diels-Alder and to expand the reactional scope by producing adducts with distinct characteristics of structures and reactivity. Fourteen different monomers were obtained in good yields in flow regime.
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format Online
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institution Universidade Estadual de Campinas
issn 2596-1969
language eng
last_indexed 2025-10-08T13:52:31Z
publishDate 2019
publisher Universidade Estadual de Campinas
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spelling ojs-article-8982025-09-26T14:32:30Z Continuous flow synthesis of terpene-based monomers for green polymers production Fernandes, Lucas Pera Pastre, Julio Cezar Galaverna, Renan Gomes, Gustavo Rodrigues Flow chemistry Diels-alder Terpenes. The synthesis of monomers for the production of novel green polymers was evaluated in continuous flow conditions using terpenes as dienes and maleic anhydride as dienophile for the [4+2] Diels-Alder cycloaddition reaction. The hydrogenation reaction was also evaluated to prevent the retro-Diels-Alder and to expand the reactional scope by producing adducts with distinct characteristics of structures and reactivity. Fourteen different monomers were obtained in good yields in flow regime. Universidade Estadual de Campinas 2019-02-12 info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion Artigo de convidado application/pdf https://econtents.sbu.unicamp.br/eventos/index.php/pibic/article/view/898 10.20396/revpibic262018898 Revista dos Trabalhos de Iniciação Científica da UNICAMP; n. 26 (2018): Congresso de Iniciação Científica Unicamp 2596-1969 eng https://econtents.sbu.unicamp.br/eventos/index.php/pibic/article/view/898/968 Copyright (c) 2019 Lucas Pera Fernandes, Julio Cezar Pastre http://creativecommons.org/licenses/by/4.0
spellingShingle Fernandes, Lucas Pera
Pastre, Julio Cezar
Galaverna, Renan
Gomes, Gustavo Rodrigues
Flow chemistry
Diels-alder
Terpenes.
Continuous flow synthesis of terpene-based monomers for green polymers production
title Continuous flow synthesis of terpene-based monomers for green polymers production
title_full Continuous flow synthesis of terpene-based monomers for green polymers production
title_fullStr Continuous flow synthesis of terpene-based monomers for green polymers production
title_full_unstemmed Continuous flow synthesis of terpene-based monomers for green polymers production
title_short Continuous flow synthesis of terpene-based monomers for green polymers production
title_sort continuous flow synthesis of terpene-based monomers for green polymers production
topic Flow chemistry
Diels-alder
Terpenes.
url https://econtents.sbu.unicamp.br/eventos/index.php/pibic/article/view/898
work_keys_str_mv AT fernandeslucaspera continuousflowsynthesisofterpenebasedmonomersforgreenpolymersproduction
AT pastrejuliocezar continuousflowsynthesisofterpenebasedmonomersforgreenpolymersproduction
AT galavernarenan continuousflowsynthesisofterpenebasedmonomersforgreenpolymersproduction
AT gomesgustavorodrigues continuousflowsynthesisofterpenebasedmonomersforgreenpolymersproduction